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          博士風采
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          劉博 博士

          發布者:  發布時間:2017年07月06日 09:36

          劉博:男,198911月出生,博士,教授。2010年畢業于吉林大學高分子材料科學與工程學院,獲得工學學士學位;同年聯合培養于吉林大學材料科學與工程學院和中科院長春應用化學研究所,于2015年獲得工學博士學位。20162月至今為新加坡南洋理工大學生物化學與工程學院博士后,開展新型高效抗菌離子液體的合成。現在長沙理工大學材料科學與工程學院工作,主要從事新型聚離子液體在生物抗菌和電解液方向的應用。

          研究領域和興趣:

          1. 以多組分反應(Debus-Radziszewski反應, Passerini反應, Schiff-base 反應,Ugi反應和亞胺化反應等)為基礎,在溫和的反應、低成本條件下,構筑具有高效抗菌性能的離子液體;離子液體作為電解液在液流電池的應用;

          2. 設計合成金屬催化劑,通過對烯烴單體的聚合的手性位點控制,制備具有高立體規整度的聚合物。探討聚合物的立體選擇性與抗菌選擇性之間的內在聯系;

          3. 通過芳香胺和芳香酸酐亞胺化反應開發均一分布的聚酰亞胺,并探討聚合物極性對分散碳納米管的性能影響,進而制備具有高機械強度和耐高溫聚合物復合材料。

          科研成果和參與項目:

          作為團隊核心成員獲得首批湖南省團隊百人計劃項目。目前,申請國際專利2項,國家發明專利2項,已獲得授權專利2項。在AngewChemInt Edit, Chemistry of materials, Macromolecules, Chemical Communications, Organometallics等國際期刊上發表科研論文近20篇。其中以第一作者發表論文10篇。首次利用稀土催化劑對可再生單體月桂烯及其衍生物亞甲基環戊二烯實現高選擇性高活性配位可控聚合,也為聚烯烴的可持續發展提供了一種新的思路。

          近五年來,博士期間先后承擔兩項國家自然科學基金可持續性聚合催化用與先進可生物再生聚合物的合成(90萬元)和稀土配位催化異戊二烯、丁二烯、苯乙烯選擇性三元共聚合制備集成橡膠(85萬元);博后期間承擔Novel antimicrobial hydrogel formulations for biomedical devices(新型抗菌水凝膠在生物醫用器件的應用,1500萬元),Selective therapy with cationic antimicrobial biomacromolecules(陽離子抗菌生物大分子的選擇性醫療,5000萬元),Hierarchical composite research(多級復合材料研究,500萬元),主持并負責Procter & Gamble(寶潔公司)聯合項目陽離子聚合物在表面活性性下的選擇性殺菌(cationic polymers selective antimicrobial with anionic surfactant500萬元)。在國內外學術刊物上發表論文20余篇,申請國家發明專利,PCT專利和美國專利共4項。近年來,作為邀請審稿人多次為ACS NanoACS Applied Materials & InterfacesBiomacromolecules進行評審工作。

           

          近五年主要論著:

          發表論文:

          1. Bo Liu and Dongmei Cui, Coordination Polymerization of Renewable 3Methylenecyclopentene with RareEarth Metal Precursors, AngewChemInt Edit, 2017, 56, 4560–4564

          2. Bo Liu, and Chengyin LiuChan Bee Eng, Mary,Using novel PLA-PI-PLA and PMCP-PI-PMCP triblock copolymers as Dispersants of Single-Walled Carbon Nanotubes for Reinforcement of Epoxy Composites, Polymer Chemistry, 2017, accepted

          3. Bo Liu, Lei Li, Guangping Sun, Jingrao Liu, Meiyan Wang, Shihui Li and Dongmei Cui,* Macromolecules, 2014, 47, 4971?4978. 3,4-Polymerization of Isoprene by Using NSN- and NPN-Ligated Rare Earth Metal Precursors: Switching of Stereo Selectivity and Mechanism

          4. Bo Liu, Lei Li, Guangping Sun, Dongtao Liu, Shihui Li and Dongmei Cui,* Chem. Commun., 2015, 51, 1039–1041. Isoselective 3,4-(co)Polymerization of Bio-renewable Myrcene Using NSN-ligated Rare-earth Metal Precursor: An Approach To a New Elastomer

          5. Bo Liu, Guangping Sun, Shihui Li, Dongtao Liu and Dongmei Cui,* Organometallics, 2015, 34: 4063-4068. Isoprene Polymerization with Iminophosphonamide Rare-Earth Metal Alkyl Complexes: Influence of Metal-Size on the Regio and Stereoselectivity

          6. Chengyin LiuBo Liu, Chan Bee Eng, Mary, Polymer Chemistry, 2017, 8, 674-681 Synthesis of Polycaprolactone-Polyimide-Polycaprolactone Triblock Copolymers via a 2-step Sequential Copolymerization and their Application as Carbon Nanotube Dispersants (共同一作,封面)

          7. Bo Liu, Shihui Li, Dongtao Liu, Guangping Sun and Dongmei Cui,* Chinese J PolymSci, 2015, Highly Trans-1,4-Selective (Co)Polymerizations of Myrcene and Isoprene by a Lanthanum dialkyl complex that Bears a Imidophosphonamido Ligand

          8. Bo Liu, Shihui Li, Danfeng Li, KuiLv, Guangping Sun and Dongmei Cui,* Chinese J Applied Chem, 2012, 29, 1394–1398. Highly 1,2-Selective Polymerization of 1,3-Butadiene with Rare-earth Metal Bis(alky)s Bearing an Iminophosphonamide Ligand

          9. Bo Liu, Chunmei Jiang, Chunling Zhang, Xuetao Bai and Jianxin Mu High Performance Polymers 2012, 24, 747–755. Octasilsesquioxane-reinforced TMBP Epoxy Nanocomposites: Characterization of Thermal, Flame-retardant, and Morphological Properties

          10. Bo Liu, Baoyu Han, Chunling Zhang, Shihui Li, Guangping Sun and Dongmei Cui,* Chinese J PolymSci, 2015, 33, 792–796. Renewable Myrcene Polymerization Initiated by Lutetium Alkyl Complexes Ligated by Imidophosphonamido Ligand (封面)

          11. Lei Li, Bo Liu, Dongtao Liu, Chunji Wu, Shihui Li, and Dongmei Cui,* Organometallics, 2014, 24, 6474–6480. Copolymerization of ε-Caprolactone and L-Lactide Catalyzed by Multinuclear Aluminum Complexes: An Immortal Approach

          專利:

          1. Chan Bee Eng, Mary, 劉博, Poly(Alkylated Imidazolium) Salts, US patent 62/486,613 (美國專利) (第一作者為導師)

          2. 崔冬梅,劉博, 國家發明專利, 201410634701.0, 2014. 一種3,4聚月桂烯的制備方法 (第一作者為導師)

          3. 崔冬梅,劉博, 國家發明專利, 201310689095.8, 2013. 稀土催化劑合成在結晶性3,4聚異戊二烯的應用 (PCT專利) (第一作者為導師)

          4. 張春玲,劉博, 國家發明專利, 201110381870.4, 2011. 環氧樹脂與籠型倍半硅氧烷雜化材料的制備(第一作者為導師)

          會議論文:

          1. Bo Liu and Chan Bee Eng, Mary,* Poster, 2016. International Conference on cellular&molecular bioengineer, Singapore

          2. Bo Liu and Dongmei Cui,* Poster, 2014. International Workshop on Catalytic Olefin Polymerization and High Performance Polyolefins, Shanghai

          3. Bo Liu and Dongmei Cui,* Poster, 2013. The 2nd Grubbs Symposium on Polymer & Catalysis, Ningbo

          4. Bo Liu and Dongmei Cui,* Poster, 2012. National Organometallic Symposium of China, Beijing

          5. Bo Liu, and Chunling Zhang,* Abstract, 2012. China Flame Retardant Academic Annual Meeting, Xiamen

           

          Emaillbb1107@126.com

          通訊地址:(郵政編碼410114)湖南省長沙市雨花區萬家麗南路二段960號材料科學與工程學院


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